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Understand Polymerisation

Worksheet Overview

Think of the most important things in your life – your phone, your music player, your vacuum cleaner (if you like having a clean bedroom). They will all be made with plastics in them. Plastics really became common in the 1960's. They were a revolution in chemistry – suddenly it was cheap and easy to make basically everything and, unlike wood and paper, plastics did not rot.


Plastic slide


We're now more aware of the pollution problems caused by plastics, and need to work hard to solve them, but plastics are still incredibly useful.


Plastic pollution


The manufacture of plastics comes from oil. Polymers are very big molecules with long chains, and they are made from many small molecules called monomers. 'Poly' means many and 'mono' means one. When you stick together lots of monomers, you get a polymer. Living things make a lot of polymers naturally - proteins, starch and DNA are all examples of natural polymers.


Plastics have names like polythene, polycarbonate, polyvinyl chloride (PVC). The 'poly' part tells you that there are lots of repeating molecules joined together. The second part of the name tells you what the monomer is. So in polythene, we have lots of ethene monomers joined in a chain.


Structure of polythene



Making polymers

The simplest sort of polymer to understand is called an addition polymer because we just add more and more monomers in a chain, one after the other. 

If we want to make polythene, we need to start with an ethene molecule to make this work. In the diagram below, on the left-hand side you can see an ethene monomer. If you look between the two carbons, you can see that there is a double bond (two lines). This is what makes an alkene. If it has a carbon-carbon double bond, then it is ripe for being made into a plastic.


The formation of polythene


All we need is a chemical reaction that breaks apart one of the double bonds in the alkene. When this is broken, it is freed up to bond with another alkene. This process means that one alkene can bond to make a chain of two, and then three and then four etc, until the chains are hundreds of bonds long. The final version of the diagram (the one with brackets) is called the displayed formula. The part in brackets repeats, the bonds sticking out will link this monomer to its neighbours, and the n at the bottom-right of the brackets tells us that there are many repeats of the monomer.


What controls the properties of the plastic?

Good question – there are two things to think about. One is the monomer used - different monomers make plastics with different properties:


Polymer Properties Uses
Polythene Flexible, cheap, electrical insulator Plastic bags, insulation for electric wires
Polypropene Flexible, strong, tough Crates, ropes, plastic furniture
Polyvinyl chloride Tough, cheap Window frames, water pipes
Polytetrafluoroethene Tough, chemically unreactive Waterproof clothing, non-stick pans


The other factor is the length of the polymer chains - longer chains mean that there are more intermolecular forces . More intermolecular forces mean that the resulting plastic is stronger, less flexible and has a higher melting point.


Property of Plastic Long Chains Short Chains
Strength Tend to be strong as there are a lot of intermolecular forces.  Tend to be weak as there are not a lot of intermolecular forces. 
Flexibility Tend to be more flexible as there are fewer branches on the polymer chains stopping them from flowing over each other.  Tend to be less flexible as there tend to be more branches on the chains that get caught up in each other and stop the flow. 
Hardness Tend to be less hard and the chains can slide over each other.  Tend to be harder as the chains cannot slide as easily.
Melting Point High melting point as there are more intermolecular forces between long chains Low melting point as there are fewer intermolecular forces between long chains


Despite their problems, plastics are still a very useful group of materials. They are made by joining together alkene molecules, which come from crude oil. That's another reason why we need to be careful how we use the planet's fossil fuel reserves.


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