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Collision theory

Worksheet Overview

QUESTION 1 of 10

The speed of a chemical reaction makes a big difference to its effects. Fireworks involve metals reacting with oxygen in a fraction of a second...

... but rusting happens over years, despite also involving metal + oxygen.

In this activity, and the next one, you will learn how we can describe this difference, and use an aspect of particle theory called collision theory to explain why some reactions are fast and some are slow. That helps people make good reactions (like pretty fireworks) go faster, and make bad reactions (like rusting) go more slowly.

Rates of reaction

Suppose we start a chemical reaction and record how much product is made over time. Unless something very strange happens, the graph will look like this;

The first part of the graph is a straight line. This is also the time when the reaction is fastest. As time passes, the reaction starts to go more slowly, then it stops. This is called completion; for the reaction in the graph, completion is at about 10 - 12 minutes. The amount of product made doesn't depend on the rate of reaction- it is fixed by the amounts of reactant put into the reaction.

The reaction rate tells us how quickly the reaction happens. To work out the rate of reaction, we calculate

rate of reaction = amount of reaction ÷ time taken

For example, in the graph, the first two minutes of the graph are pretty much a straight line, In that time, the reaction makes 9 cm3 gas, so

initial rate of reaction = 9 cm3 ÷ 2 min = 4.5 cm3 / min. Since 2 min = 120 s, we could also write this as

initial rate of reaction = 9 cm÷ 120 s = 0.075 cm3 / s.

As the reaction progresses, the rate of reaction slows down. The graph shows this by becoming less steep.

A better way to use the graph (and the only way that works when the graph is noticeably curved) is to draw the tangent to the graph at the moment of interest. So let's take another graph. What is the rate for this reaction at t = 40 seconds?

The red dotted line is the tangent to the graph at x = 40 seconds; it's a straight line which touches the graph at 40 seconds, without cutting it. The gradient of the graph at that moment is the same as the gradient of the tangent. But since the tangent is a straight line, we can work out its gradient using up ÷ across. Just remember that in science graphs, the up and across numbers need to relate to the numbers on the axes; you can't just count squares.

The tangent line goes from 7 cm3 at t = 0 s to 30 cm3 at t = 95 s. So the up is 30 - 7 = 23 cm3, and the across = 95 - 0 = 95 s. That means the gradient of the tangent = 23 ÷ 95 = 0.24 cm3 / s.

So the rate of reaction at 40 s = 0.24 cm3 / s.


Collision theory

There are several factors which change the rate of reaction. One big idea links them all, called collision theory.

For two particles to react, they have to collide, in the right orientation and with enough energy to break the atomic bonds in the particles.

The more frequently these collisions happen, the faster the rate of reaction will be.

Once we understand collision theory, we can explain why some reactions are fast and some are slow. We can also speed up or slow down reactions if that is what we need to do.

To speed up a reaction, we just need to make useful collisions happen more frequently. There are several ways of doing this, which you will learn about in another activity.


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